2-oxo-3-hexenedioate decarboxylase EC#: 4.1.1.77; ChemWhat Code: 1381981

Product Name 2-oxo-3-hexenedioate decarboxylase
Example Structure Example Structure of 2-oxo-3-hexenedioate decarboxylase EC#: 4.1.1.77
Synonyms 4-OD, 4-oxalocrotonate decarboxylase, 4OD, Decarboxylase, 4-oxalocrotonate, NahK, Oxalocrotonate decarboxylase
EC Number 4.1.1.77
CAS Registry Number 37325-55-6
Comments Involved in the meta-cleavage pathway for the degradation of phenols, modified phenols and catechols. The enzyme has been reported to accept multiple tautomeric forms [1-4]. However, careful analysis of the stability of the different tautomers, as well as characterization of the enzyme that produces its substrate, EC?5.3.2.6, 2-hydroxymuconate tautomerase, showed that the actual substrate for the enzyme is (3E)-2-oxohex-3-enedioate [4].
Cofactor
History
Reactions (3E)-2-oxohex-3-enedioate = 2-oxopent-4-enoate + CO(2).

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