3-Methyl-6-oxo-1-phenyl-6,7-dihydro-1H-pyrazolo[3,4-b]pyridine-5-carbonitrile CAS#: 52217-38-6; ChemWhat Code: 1490352
Identification
Product Name | 3-Methyl-6-oxo-1-phenyl-6,7-dihydro-1H-pyrazolo[3,4-b]pyridine-5-carbonitrile |
IUPAC Name | 3-methyl-6-oxo-1-phenyl-7H-pyrazolo[3,4-b]pyridine-5-carbonitrile |
Molecular Structure | |
CAS Registry Number | 52217-38-6 |
EINECS Number | No data available |
MDL Number | MFCD11890435 |
Beilstein Registry Number | No data available |
Synonyms | 6,7-dihydro-3-methyl-6-oxo-1-phenyl-1H-pyrazolo[3,4-b]pyridine-5-carbonitrile |
Molecular Formula | C14H10N4O |
Molecular Weight | 250.26 |
InChI | InChI=1S/C14H10N4O/c1-9-12-7-10(8-15)14(19)16-13(12)18(17-9)11-5-3-2-4-6-11/h2-7H,1H3,(H,16,19) |
InChI Key | ZLQQCJLXBVVVMR-UHFFFAOYSA-N |
Canonical SMILES | Cc1nn(-c2ccccc2)c2[nH]c(=O)c(C#N)cc12 |
Patent Information |
No data available |
Physical Data
Appearance | White powder |
Solubility | No data available |
Flash Point | No data available |
Refractive index | No data available |
Sensitivity | No data available |
Melting Point, °C | Solvent (Melting Point) |
190 | ethanol |
306 – 308 | acetic acid |
316 |
Boiling Point, °C |
251 |
250 – 252 |
Density, g·cm-3 | Reference Temperature, °C | Measurement Temperature, °C |
1.14 | 4 | 25 |
1.2 | 4 | -190 |
1.24 |
Description (Association (MCS)) | Solvent (Association (MCS)) | Temperature (Association (MCS)), °C | Partner (Association (MCS)) |
Stability constant of the complex with … | CCl4 | 24.9 | 4-Fluorophenol |
Stability constant of the complex with … | aq. HNO3 | 25 | AgNO3 |
Enthalpy of association | acetonitrile | 25 | iodine |
NMR spectrum of the complex | CDCl3 | Cu(2,4-dichloro-benzoate)2 |
Spectra
Description (NMR Spectroscopy) | Nucleus (NMR Spectroscopy) | Solvents (NMR Spectroscopy) | Frequency (NMR Spectroscopy), MHz |
Chemical shifts | 1H | dimethylsulfoxide-d6 | 500 |
Chemical shifts | 13C | dimethylsulfoxide-d6 | 126 |
Chemical shifts | 1H | CDCl3 | |
Chemical shifts | 1H | trifluoroacetic acid |
Description (IR Spectroscopy) | Solvent (IR Spectroscopy) | Temperature (IR Spectroscopy), °C |
Bands | KBr | 3340 – 1710 cm**(-1) |
Bands | KBr | 3600 – 1663 cm**(-1)3600 – 1663 cm**(-1) |
Description (Mass Spectrometry) |
high resolution mass spectrometry (HRMS), electrospray ionisation (ESI), spectrum |
Description (UV/VIS Spectroscopy) | Solvent (UV/VIS Spectroscopy) | Absorption Maxima (UV/VIS), nm | Ext./Abs. Coefficient, l·mol-1cm-1 |
Absorption maxima | ethanol | 264, 315 | 23988, 8511 |
Route of Synthesis (ROS)
Conditions | Yield |
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 4h; | 85% |
Safety and Hazards
GHS Hazard Statements | Not Classified |
Other Data
Transportation | NONH for all modes of transport |
Under the room temperature and away from light | |
HS Code | |
Storage | Under the room temperature and away from light |
Shelf Life | 2 years |
Market Price | USD |
Druglikeness | |
Lipinski rules component | |
Molecular Weight | 250.26 |
logP | 1.894 |
HBA | 5 |
HBD | 1 |
Matching Lipinski Rules | 4 |
Veber rules component | |
Polar Surface Area (PSA) | 70.71 |
Rotatable Bond (RotB) | 1 |
Matching Veber Rules | 2 |
Use Pattern |
It is a derivative of edaravone and is often used as a pharmaceutical intermediate. |
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