alpha-D-ribose 1-methylphosphonate 5-phosphate C-P-lyase EC#: 4.7.1.1; ChemWhat Code: 1383001

Product Name alpha-D-ribose 1-methylphosphonate 5-phosphate C-P-lyase
Example Structure Example Structure of alpha-D-ribose 1-methylphosphonate 5-phosphate C-P-lyase EC#: 4.7.1.1
Synonyms P279_10500, phnJ
EC Number 4.7.1.1
CAS Registry Number
Comments This radical SAM (AdoMet) enzyme is part of the C-P lyase complex, which is responsible for processing phophonates into usable phosphate. Contains an [4Fe-4S] cluster. The enzyme from the bacterium?Escherichia coli?can act on additional ¦Á-D-ribose phosphonate substrates with different substituents attached to the phosphonate phosphorus (e.g. ¦Á-D-ribose-1-[N-(phosphonomethyl)glycine]-5-phosphate and ¦Á-D-ribose-1-(2-N-acetamidomethylphosphonate)-5-phosphate).
Cofactor S-adenosyl-L-methionine iron-sulfur
History
Reactions Alpha-D-ribose 1-methylphosphonate 5-phosphate + S-adenosyl-L-methionine + reduced electron acceptor = alpha-D-ribose 1,2-cyclic phosphate 5-phosphate + methane + L-methionine + 5′-deoxyadenosine + electron acceptor.

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