dapdiamide synthase EC#: 6.3.2.47; ChemWhat Code: 1383788

Product Name dapdiamide synthase
Example Structure Example Structure of dapdiamide synthase EC#: 6.3.2.47
Synonyms DdaF, {[(2E)-4-amino-4-oxobut-2-enoyl]amino}-L-alanine:L-valine ligase (ADP-forming)
EC Number 6.3.2.47
CAS Registry Number
Comments The enzyme, characterized from the bacterium?Pantoea agglomerans, is involved in biosynthesis of dapdiamide tripeptide antibiotics, a family of fumaramoyl- and epoxysuccinamoyl-peptides named for the presence of an (S)-2,3-diaminopropanoate (DAP) moiety and two amide linkages in their scaffold.
Cofactor
History
Reactions (1) Atp + 3-((((2R,3R)-3-carboxyoxiran-2-yl)carbonyl)amino)-L-alanine + L-valine = Adp + phosphate + 3-((((2R,3R)-3-carboxyoxiran-2- yl)carbonyl)amino)-L-alanyl-L-valine. (2) Atp + 3-(((2E)-4-amino-4-oxobut-2-enoyl)amino)-L-alanine + L-valine = Adp + phosphate + 3-(((2E)-4-amino-4-oxobut-2-enoyl)amino)-L-alanyl-L- valine. (3) Atp + 3-(((2E)-4-amino-4-oxobut-2-enoyl)amino)-L-alanine + L-isoleucine = Adp + phosphate + 3-(((2E)-4-amino-4-oxobut-2- enoyl)amino)-L-alanyl-L-isoleucine. (4) Atp + 3-(((2E)-4-amino-4-oxobut-2-enoyl)amino)-L-alanine + L-leucine

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