L-tyrosine isonitrile synthase EC#: 4.1.99.24; ChemWhat Code: 1382223
| Product Name | L-tyrosine isonitrile synthase |
| Example Structure |  |
| Synonyms | pvcA |
| EC Number | 4.1.99.24 |
| CAS Registry Number | |
| Comments | The enzymes from the bacteria?Pseudomonas aeruginosa?and?Xenorhabdus nematophila?are involved in the biosynthesis of paerucumarin and rhabduscin, respectively. According to the proposed mechanism, the enzyme forms an imine intermediate composed of linked?L-tyrosine and?D-ribulose 5-phosphate, followed by loss of the phosphate group and formation of a ¦Â-keto imine and keto-enol tautomerization. This is followed by a C-C bond cleavage, the release of acetol, and a retro aldol type reaction that releases formaldehyde and forms the final product [3].?cf. EC?4.1.99.25,?L-tryptophan isonitrile synthase. |
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