(S)-cheilanthifoline synthase EC#: 1.14.19.65; ChemWhat Code: 1375830

Product Name (S)-cheilanthifoline synthase
Example Structure Example Structure of (S)-cheilanthifoline synthase EC#: 1.14.19.65
Synonyms (S)-scoulerine oxidase (methylenedioxy-bridge-forming), cheilanthifoline synthase, CYP719A13, CYP719A14, CYP719A5, EC 1.1.3.33, S-cheilanthifoline synthase, synthase, (S)-cheilanthifoline
EC Number 1.14.19.65
CAS Registry Number 138791-27-2
Comments A cytochrome P450 (heme-thiolate) protein catalysing an oxidative reaction that does not incorporate oxygen into the product. Forms the methylenedioxy bridge of the protoberberine alkaloid cheilanthifoline by the oxidative ring closure of adjacent phenolic and methoxy groups of scoulerine. cf. EC 1.14.19.73, (S)-nandinine synthase, which catalyses a similar reaction at the other side of the (S)-scoulerine molecule, forming (S)-nandinine.
Cofactor heme-thiolate
History
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