syn-copalyl-diphosphate synthase EC#: 5.5.1.14; ChemWhat Code: 1383490

Product Name syn-copalyl-diphosphate synthase
Example Structure Example Structure of syn-copalyl-diphosphate synthase EC#: 5.5.1.14
Synonyms CPS4, OsCPSsyn, OsCyc1, syn-CDP synthase, syn-copalyl diphosphate lyase (decyclizing), syn-copalyl diphosphate synthase, syn-CPP synthase
EC Number 5.5.1.14
CAS Registry Number
Comments Requires a divalent metal ion, preferably Mg2+, for activity. This class II terpene synthase produces syn-copalyl diphosphate, a precursor of several rice phytoalexins, including oryzalexin S and momilactones A and B. Phytoalexins are diterpenoid secondary metabolites that are involved in the defense mechanism of the plant, and are produced in response to pathogen attack through the perception of elicitor signal molecules such as chitin oligosaccharide, or after exposure to UV irradiation. The enzyme is constitutively expressed in the roots of plants where one of its products, momilactone B, acts as an allelochemical (a molecule released into the environment to suppress the growth of neighbouring plants). In other tissues the enzyme is upregulated by conditions that stimulate the biosynthesis of phytoalexins.
Cofactor Mg2+
History
Reactions Geranylgeranyl diphosphate = 9-alpha-copalyl diphosphate.

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